Phosphine-imine and-enamido ligands for acceptorless dehydrogenation catalysis

Authors

J. M. Stubbs, The University of Western Ontario
K. F. Firth, The University of Western Ontario
B. J. Bridge, The University of Western Ontario
K. J. Berger, The University of Western Ontario
R. J. Hazlehurst, The University of Western Ontario
P. D. Boyle, The University of Western Ontario
J. M. Blacquiere, The University of Western OntarioFollow

Document Type

Article

Publication Date

1-1-2017

Journal

Dalton Transactions

Volume

46

Issue

3

First Page

647

Last Page

650

URL with Digital Object Identifier

10.1039/c6dt04088h

Abstract

A highly tunable phosphine-imine ligand family is introduced. Following metallation with ruthenium, deprotonation of the ligand affords a phosphine-enamido species. Complexes with the ligand in both the imine and enamido forms are active toward acceptorless dehydrogenation reactions.

Notes

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CSC100: Celebrating Canadian Chemistry

Citation of this paper:

J.M. Stubbs,^† K.F. Firth,^† B.J. Bridge, K.J. Berger, R.J. Hazlehurst, P.D. Boyle and J.M. Blacquiere, "Phosphine-Imine and -Enamido Ligands for Acceptorless Dehydrogenation Catalysis"

28 Nov 2016 Dalton Trans., 2017,46, 647-650 https://doi.org/10.1039/C6DT04088H