Chemistry Publications

Title

C(sp3)-C(sp3) Coupling with a Pd(II) Complex Bearing a Structurally Responsive Ligand

Document Type

Article

Publication Date

4-22-2019

Journal

Organometallics

Volume

38

Issue

8

First Page

1677

Last Page

1681

URL with Digital Object Identifier

10.1021/acs.organomet.9b00014

Abstract

A dimer with two PdII-Me fragments is stabilized by the bridging coordination of the supporting 1-azaallyl/phosphine ligand. Heating the complex results in C(sp3)-C(sp3) bond formation and the release of ethane. Two different palladium products are generated, each with distinct coordination modes of the 1-azaallyl/phosphine ligand.

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