C(sp³)-C(sp³) Coupling with a Pd(II) Complex Bearing a Structurally Responsive Ligand

Authors

Kyle M.K. Jackman, The University of Western Ontario
Benjamin J. Bridge, The University of Western Ontario
Ethan R. Sauve, The University of Western Ontario
Christopher N. Rowley, Memorial University of Newfoundland
Cameron H.M. Zheng, The University of Western Ontario
James M. Stubbs, The University of Western Ontario
Paul D. Boyle, The University of Western Ontario
Johanna M. Blacquiere, The University of Western OntarioFollow

Document Type

Article

Publication Date

4-22-2019

Journal

Organometallics

Volume

38

Issue

8

First Page

1677

Last Page

1681

URL with Digital Object Identifier

10.1021/acs.organomet.9b00014

Abstract

A dimer with two PdII-Me fragments is stabilized by the bridging coordination of the supporting 1-azaallyl/phosphine ligand. Heating the complex results in C(sp3)-C(sp3) bond formation and the release of ethane. Two different palladium products are generated, each with distinct coordination modes of the 1-azaallyl/phosphine ligand.