Chemistry Publications

Document Type

Article

Publication Date

7-29-2010

Journal

Organic letters

Volume

12

Issue

16

First Page

3658

Last Page

3661

URL with Digital Object Identifier

10.1021/ol101453e

Abstract

The synthesis of siloles with substitution patterns that are continuative toward natural product synthesis are described. Their reactivity in Diels-Alder chemistry was explored through thermal, Lewis acid, and high-pressure reactions. Furthermore, bicyclic adducts were oxidatively cleaved to reveal a highly functionalized cyclohexene core.


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