Faculty

Science

Supervisor Name

Yang Song

Keywords

two-dimensional perovskite, high pressure, solar cells, phase change, metastable

Description

Two-Dimensional Perovskites are semiconductors and are of interest to researchers as the class of materials show great promise for innovating improvements to solar cells. The purpose of this experiment is to determine if a metastable change will occur in the materials: DPDAPbI4 and CMA2PbI4 upon compression to approximately 9 GPa. The experiment was conducted using diamond anvil cells (DAC) to apply static pressure to the materials. The pressure of the sample was then measured using ruby fluorescence. Then, FTIR or Raman spectroscopy acquisitions were obtained at various pressures. Subsequently, the data suggests that a metastable change did not occur. Additionally, the materials underwent a reversible amorphization and potential phase changes were observed in both materials.

Acknowledgements

Prof. Song, Jesse Ratte

Creative Commons License

Creative Commons Attribution-Noncommercial 4.0 License
This work is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 4.0 License.

Document Type

Poster

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Structural Tuning of Two-Dimensional Perovskites at High Pressure

Two-Dimensional Perovskites are semiconductors and are of interest to researchers as the class of materials show great promise for innovating improvements to solar cells. The purpose of this experiment is to determine if a metastable change will occur in the materials: DPDAPbI4 and CMA2PbI4 upon compression to approximately 9 GPa. The experiment was conducted using diamond anvil cells (DAC) to apply static pressure to the materials. The pressure of the sample was then measured using ruby fluorescence. Then, FTIR or Raman spectroscopy acquisitions were obtained at various pressures. Subsequently, the data suggests that a metastable change did not occur. Additionally, the materials underwent a reversible amorphization and potential phase changes were observed in both materials.

 

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