Chemistry Publications

Title

Addition of alkynes to digermynes: Experimental insight into the reaction pathway

Document Type

Article

Publication Date

5-7-2016

Journal

Dalton Transactions

Volume

45

Issue

17

First Page

7226

Last Page

7230

URL with Digital Object Identifier

10.1039/c6dt01015f

Abstract

The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes.

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