Chemistry Publications

Title

The Addition of a Cyclopropyl Alkyne to an Asymmetrically-Substituted Disilene: A Mechanistic Study

Document Type

Article

Publication Date

4-8-2019

Journal

Organometallics

Volume

38

Issue

7

First Page

1622

Last Page

1626

URL with Digital Object Identifier

10.1021/acs.organomet.9b00054

Abstract

The addition of (2-ethynyl-3-methoxy-2-methylcyclopropyl)benzene to Tip Si=SiTipPh, a disilene with an asymmetric substitution pattern, was investigated. The regiochemistry of the ring-opened products indicates a stepwise mechanism with a biradical intermediate. The results are consistent with those obtained in similar experiments with symmetrically substituted disilenes. 2

This document is currently not available here.

Share

COinS