Chemistry Publications

Document Type

Article

Publication Date

Spring 4-13-2017

Journal

Organometallics

Volume

36

Issue

14

First Page

2483

Last Page

2486

URL with Digital Object Identifier

DOI: 10.1021/acs.organomet.7b00085

Abstract

An organometallic homopolymer containing three different metals per repeating unit was synthesized from an air- and moisture-stable secondary phosphine bearing ethylferrocene and ethylruthenocene groups. Hydrophosphination yielded a tertiary phosphine bearing an alcohol, which was then used to introduce a polymerizable styrene group via DCC coupling. Free-radical polymerization, followed by post-polymerization coordination to photogenerated W(CO)5 units yielded the title polymer, which showed thermal, spectroscopic, and electrochemical properties associated with each of the transition metals involved.

Available for download on Tuesday, May 01, 2018


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